Preheat the oven to 350°F (175°C). Grease and lightly flour a 9×13-inch baking pan, or line it with parchment paper.
In a large mixing bowl, whisk together the flour, cocoa powder, sugar, baking soda, baking powder, salt, and cinnamon until well combined.
In a separate bowl, whisk together the buttermilk, brewed coffee, vegetable oil, eggs, and vanilla extract until smooth.
Add the wet ingredients to the dry ingredients and mix until just combined. Do not overmix.
Pour the batter into the prepared 9×13-inch pan and spread it evenly.
Bake for 35–40 minutes, or until a toothpick inserted into the center comes out clean or with a few moist crumbs attached.
Let the cake cool completely in the pan before frosting with your favorite chocolate frosting.